Synthesis, Characterization and Crystal Structure of a new Cobalt Borophosphate, NaCoH2BP2O9
Identifieur interne : 000964 ( Main/Exploration ); précédent : 000963; suivant : 000965Synthesis, Characterization and Crystal Structure of a new Cobalt Borophosphate, NaCoH2BP2O9
Auteurs : Abderrahmen Guesmi [Tunisie] ; A. Driss [Tunisie]Source :
- Advanced Engineering Materials [ 1438-1656 ] ; 2004-10.
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- Pascal (Inist)
English descriptors
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Abstract
A new sodium cobalt hydrogen borophosphate, NaCoH2BP2O9, was synthesized by the mild hydrothermal method and the crystal structure was characterized by the single‐crystal x‐ray diffraction method]. The structure consists in anionic groups [(H2BP2O9)3‐]2 (centrosymmetric units [HP(2)O3O1/2‐HBO2O2/2‐P(1)O3O1/2]2) which are interconnected by sharing corners with the Co2O10 bioctahedral units. The framework connection is reinforced by hydrogen bonds.
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DOI: 10.1002/adem.200400088
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Le document en format XML
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<profileDesc><textClass><keywords scheme="KwdEn" xml:lang="en"><term>Bond angle</term>
<term>Borates</term>
<term>Borophosphates</term>
<term>Centrosymmetrical crystals</term>
<term>Crystal growth</term>
<term>Crystal structure</term>
<term>Crystal structures</term>
<term>Hydrogen bonds</term>
<term>Hydrothermal growth</term>
<term>Interatomic distances</term>
<term>Monocrystals</term>
<term>XRD</term>
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<keywords scheme="Pascal" xml:lang="fr"><term>6166F</term>
<term>Angle liaison</term>
<term>B Co H Na O P</term>
<term>Cobalt hydrogénoborophosphate</term>
<term>Cristal centrosymétrique</term>
<term>Croissance cristalline</term>
<term>Diffraction RX</term>
<term>Distance interatomique</term>
<term>Liaison hydrogène</term>
<term>Monocristal</term>
<term>Méthode hydrothermale</term>
<term>NaCoH2BP2O9</term>
<term>Sodium hydrogénoborophosphate</term>
<term>Structure cristalline</term>
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<front><div type="abstract" xml:lang="en">A new sodium cobalt hydrogen borophosphate, NaCoH2BP2O9, was synthesized by the mild hydrothermal method and the crystal structure was characterized by the single‐crystal x‐ray diffraction method]. The structure consists in anionic groups [(H2BP2O9)3‐]2 (centrosymmetric units [HP(2)O3O1/2‐HBO2O2/2‐P(1)O3O1/2]2) which are interconnected by sharing corners with the Co2O10 bioctahedral units. The framework connection is reinforced by hydrogen bonds.</div>
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