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Synthesis, Characterization and Crystal Structure of a new Cobalt Borophosphate, NaCoH2BP2O9

Identifieur interne : 000964 ( Main/Exploration ); précédent : 000963; suivant : 000965

Synthesis, Characterization and Crystal Structure of a new Cobalt Borophosphate, NaCoH2BP2O9

Auteurs : Abderrahmen Guesmi [Tunisie] ; A. Driss [Tunisie]

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RBID : ISTEX:EA64A9A342D62D47711829000201DD9E3F2A1475

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Abstract

A new sodium cobalt hydrogen borophosphate, NaCoH2BP2O9, was synthesized by the mild hydrothermal method and the crystal structure was characterized by the single‐crystal x‐ray diffraction method]. The structure consists in anionic groups [(H2BP2O9)3‐]2 (centrosymmetric units [HP(2)O3O1/2‐HBO2O2/2‐P(1)O3O1/2]2) which are interconnected by sharing corners with the Co2O10 bioctahedral units. The framework connection is reinforced by hydrogen bonds.

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DOI: 10.1002/adem.200400088


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Le document en format XML

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